Includes bibliographical references and index.
|Statement||James E. McGrath, editor.|
|Series||ACS symposium series,, 166|
|Contributions||McGrath, James E., American Chemical Society. Division of Polymer Chemistry., American Chemical Society.|
|LC Classifications||QD380 .A54|
|The Physical Object|
|Pagination||xiii, 592 p. :|
|Number of Pages||592|
|LC Control Number||81014911|
About this book. This book presents these important facts: a) The mechanism of anionic polymerization, a more than year challenge in polymer chemistry, has now become better understood; b) Precise synthesis of many polymers with novel architectures (triblock, multi-block, graft, exact graft, comb, cyclic, many armed stars with multi-components, dendrimer-like hyper-branched, . Extra info for Anionic Polymerization. Kinetics, Mechanisms, and Synthesis. Sample text. Styrene a % 1,4 80 80 75 68 66 60 30 32 36 51 45 52 82 95 30 16 copolymer a t equimolar charge ratio. s o l v e n t s, s u c h a s e t h e r s, t h e p r o p a g a t i n g c h a i n ends a r e i o n p a i r s i n e q u i l i b r i u m with free anions/5(17). Anionic polymerization-- kinetics, mechanisms, and synthesis: based on a symposium sponsored by the Division of Polymer chemistry at the th meeting . Book Description This work introduces the basic theories and experimental methods of anionic polymerization as well as the synthesis, analysis and characteristics of anionic polymerized products. It details the creation of linear and branched polymers, random and block copolymers, graft and macromonomers, and many other substances.
Anionic Polymerization: Principles and Practice describes the unique nature of the anionic mechanism of polymerization. This book is composed of two parts encompassing 11 chapters that cover the aspects of the synthetic possibilities inherent in this system. Get this from a library! Anionic polymerization: kinetics, mechanisms, and synthesis: based on a symposium sponsored by the Division of Polymer chemistry at the th meeting of the American Chemical Society, March , [James E McGrath; American Chemical Society. Division of Polymer Chemistry.; American Chemical Society. Meeting;]. Anionic polymerization is used to produce the styrenic block copolymers and produces a polymer with an extremely narrow block and overall molecular weight distributions. The narrow molecular weight distributions are extremely useful in fundamental studies of polymers, and have led to a great deal of study of anionic polymerization, much more than justified by its commercial importance. This work introduces the basic theories and experimental methods of anionic polymerization as well as the synthesis, analysis and characteristics of anionic polymerized products. It details the creation of linear and branched polymers, random and block copolymers, graft and macromonomers, and many other substances.
Anionic addition polymerization is a form of chain-growth polymerization or addition polymerization that involves the polymerization of monomers initiated with anions. The type of reaction has many manifestations, but traditionally vinyl monomers are used. Often anionic polymerization involves living polymerizations, which allows control of structure and composition. Anionic Polymerization of ∈-Caprolactone for Block Copolymer Synthesis YUYA YAMASHITA Chap DOI: /bkch Publication Date (Print): Novem Content: Ring-opening polymerization: introduction / James E. McGrath --Anionic polymerization of cyclosiloxanes with cryptates as counterions / Sylvie Boileau --Anionic polymerization of ethylene oxide with lithium catalysts: solution properties of styrene-ethylene oxide block polymers / Roderic P. Quirk and Norman S. Seung --Free radical ring-opening polymerization / William J. Bailey. The kinetics of the anionic polymerization of methylmethacrylate in tetrahydrofuran at −75 are investigated. Cumylcaecium, α-methylstryrylcaesium and α-methylstyrylsodium were used as : Roderic Quirk.